Particulate characteristics of laser ignited hydrogen enriched compressed natural gas engine

Laser ignition (LI) is emerging as a strong technology to control the oxides of nitrogen (NOx) emissions from spark ignition (SI) engines without the need for any significant exhaust gas after-treatment and is an appropriate technology for meeting future emission norms in the automotive sector. In this study, particulate characteristics of LI engine fuelled with different compressed natural gas (CNG) and hydrogen mixtures [100% CNG, 10HCNG (10% v/v hydrogen with 90% v/v CNG), 30HCNG (30% v/v hydrogen with 70% v/v CNG), 50HCNG (50% v/v hydrogen with 50% v/v CNG) and 100% hydrogen] were investigated. Experiments were performed in a suitably modified single cylinder engine, which operated in LI mode at constant engine speed (1500 rpm) at five different engine loads (5, 10, 15, 20 and 25 Nm). Particulate characteristics were determined using an engine exhaust particle sizer (EEPS). Results showed that particle number concentration increased with increasing engine load. Number-size, surface area-size and mass-size distributions of particulates reflected that addition of hydrogen in the CNG improved particulate emission characteristics especially in nucleation mode particle (NMP) size range (10 nm < Dp < 50 nm). Among the test fuels, hydrogen-fuelled engine emitted the lowest number of particles. It was observed that the difference between particulate characteristics emitted by different test fuels reduced at higher engine loads. Significant contribution of lubricating oil in particulate emissions from both hydrogen as well as HCNG fuelled LI engine was an important finding of this study. Dominant contribution of larger particles (Dp > 50 nm) in total particle mass (TPM) was an important observation of this study. The qualitative correlation between total particle number (TPN) and TPM indicated that suitable fuel composition at different engine loads yielded cleaner exhaust from the LI engine. Overall, this study demonstrated that addition of hydrogen in CNG is advantageous from particulate reduction point of view, however, optimum fuel composition should be adjusted according to engine operating condition in order to reduce particulate emissions.     

Flexible and transparent capacitors based on gel-type natural polymers

In this work, we study the capacitive properties of gel-type natural abundant polymers without any dopants, mainly commercial gelatin and agar in deionized water. Here, we propose a facile fabrication of flexible, transparent, and planar electrolytic capacitors using these gel-type and indium tin oxide thin films as electrodes deposited on poly(ethylene terephthalate) substrates. Through cyclic voltammetry and galvanostatic charge–discharge techniques, we found that the devices show a specific capacitance in the order of the millifarads per gram, a specific power of ~10 mW cm⁻², which is sufficient to active low-power devices, and a life cycle with nearly 100% efficiency after 1,000 cycles. We found that we do not need to add dopants that improve the ionic conductivity of the natural polyelectrolytes to obtain capacitances within the millifarads per gram. The flexibility of the capacitors was demonstrated by bending them, after which they exhibited the same electrochemical performance as the unbent devices. The optical transparency of the capacitors was measured by UV–V is spectroscopy showing a high transmittance in the visible region.     

The use of natural (Pinus pinaster) resin in the production of printing ink and the printability effect

Alkyd resins are generally used in the production of printing inks. All industries look for alternative raw materials in the production of ink with the growing inclination toward using natural products. Resins forming the vehicle of the ink to be obtained from natural resources will provide benefits for the environment, nature, and living creatures. The aim of the study was to promote the use of natural resin in the ink system. Natural Pinus pinaster resin was added into vegetable and mineral oil-based solvents in pure form with alkyd resin in different amounts and ink varnishes of different combinations were prepared. Then, printing inks were produced from these varnishes in pure and hybrid form. Following the assessment of the rheological properties of the inks prepared, printing tests were conducted to assess the printing quality parameters. Ideal mixing ratios of the natural resins in the ink were determined for printability. The environmental importance and advantages of the use of natural resins were discussed. Recommendations were given in line with the results to encourage widespread use of natural resins in near future.     

Numerical modelling and optimisation of natural convection heat loss suppression in a solar cavity receiver with plate fins

This study details the numerical modelling and optimization of natural convection heat suppression in a solar cavity receiver with plate fins. The use of plate fins attached to the inner aperture surface is presented as a possible low cost means of suppressing natural convection heat loss in a cavity receiver. In the first part of the study a three-dimensional numerical model that captures the heat transfer and flow processes in the cavity receiver is analyzed, and the possibilities of optimization were then established. The model is laminar in the range of Rayleigh number, inclination angle, plate height and thickness considered. In the second part of the study, the geometric parameters considered were optimized using optimization programme with search algorithm. The results indicate that significant reduction on the natural convection heat loss can be achieved from cavity receivers by using plate fins, and an optimal plate fins configuration exit for minimal natural convection heat loss for a given range of Rayleigh number. Reduction of up to a maximum of 20% at 0° receiver inclination was observed. The results obtained provide a novel approach for improving design of cavity receiver for optimal performance.     

食品药品来源的CFTR氯离子通道抑制剂的研究进展

CFTR氯离子通道是目前国际上新兴的治疗分泌型腹泻的分子药靶,CFTR抑制剂通过阻断离子通道的过度分泌来治疗腹泻症状。由于其抑制剂极为稀少,因此CFTR抑制剂的筛选工作是相关领域中最基础、最关键的环节。天然产物兼具结构和生物活性的多样性,在新药和先导化合物的发现中起着重要作用,是药物开发的主要来源,而食品药品来源的天然产物更因为对人体安全无毒副作用而倍受青睐。食品药品来源的CFTR氯离子通道抑制剂对于CFTR相关的腹泻等疾病的机理研究和治疗具有重要价值,同时也为天然产物资源用于现代药物发现提供了依据。     

Natural Gas Production

Current data on natural gas production, as well as a breakdown of production by country. Updated on a monthly basis.     

天然包装材料在食品包装设计中的应用

针对塑料、纸质、金属等食品包装材料各自的弊端和问题,阐述了食品包装材料减量化、单一化、轻型化、无毒无害化发展趋势,指出天然包装材料在食品包装中的应用范围及性能,揭示了天然包装材料的审美价值,提出了天然包装材料的选用原则和应用原则。     

Life Cycle Assessment of Substitute Natural Gas production from biomass and electrolytic hydrogen

The synthesis of a Substitute Natural Gas (SNG) that is compatible with the gas grid composition requirements by using surplus electricity from renewable energy sources looks a favourable solution to store large quantities of electricity and to decarbonise the gas grid network while maintaining the same infrastructure. The most promising layouts for SNG production and the conditions under which SNG synthesis reduces the environmental impacts if compared to its fossil alternative is still largely untapped. In this work, six different layouts for the production of SNG and electricity from biomass and fluctuating electricity are compared from the environmental point of view by means of Life Cycle Assessment (LCA) methodology. Global Warming Potential (GWP), Cumulative Energy Demand (CED) and Acidification Potential (AP) are selected as impact indicators for this analysis. The influence of key LCA methodological aspects on the conclusions is also explored. In particular, two different functional units are chosen: 1 kg of SNG produced and 1 MJ of output energy (SNG and electricity). Furthermore, different approaches dealing with co-production of electricity are also applied. The results show that the layout based on hydrogasification has the lowest impacts on all the considered cases apart from the GWP and the CED with SNG mass as the functional unit and the avoided burden approach. Finally, the selection of the multifunctionality approach is found to have a significant influence on technology ranking.     

Grape skin extracts as a sustainable source of antioxidants in an oil-in-water emulsion: an alternate natural approach to synthetic antioxidants using principal component analysis

Grape (Kyoho) skin, used to retard lipid oxidation in edible oil foods, was investigated to reduce lipid oxidation in an oil-in-water (O/W) emulsion during 20 day of storage. The antioxidant efficacy of Kyoho skin extracts in O/W emulsions was determined by the measurement of secondary oxidation products. Moreover, principal component analysis (PCA) was conducted to determine similarities between emulsions treated with or without Kyoho skin extracts and standards. The data revealed that Kyoho skin extracts exhibited >93% inhibition and reported a similar p-anisidine (4.30–20.71) and TBARS (6.08–11.15 mg MDA L⁻¹) values over the standards during 20 day of storage. PCA (PCs 1 (51.83%) and 2 (18.85%)) demonstrated a similarity in the contribution of Kyoho skin extracts over the synthetic antioxidants in O/W emulsion. Overall, these findings highlighted the possibility of using Kyoho skin extracts as natural antioxidants to decrease oxidative rancidity in foods.